Nucleophilic, anionic boryl compounds are long-sought but elusive species. We report that reductive cleavage of the boron-bromine bond in N,N′-bis(2,6-diisopropylphenyl)-2-bromo-2,3-dihydro-1H-1,3, ...
Researchers have produced the first “naked” aryl anion in solution—a carbanion not linked to counterions or stabilized by hydrogen bonding. Until now, many chemists believed such a species couldn’t ...
Scientists at Tokyo Institute of Technology developed a new strategy for producing a wide range of organotin compounds, which are the building blocks of many organic synthesis methods. Their approach ...